Abstract
An appropriate adsorption isotherm for the adsorption of benzotriazole on to copper surfaces from ammonium chloride solutions is presented. The analysis, which has taken into account the relative size factor, leads to the appropriate isotherm being that due to Frumkin. Some thermodynamic parameters of the adsorption isotherm are thus evaluated.
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References
1.
Walker
R.
, Corrosion. , 1973 , 29 , 290
2.
Dugdale
J.
, &
Cotton
J. B.
Corros. Sci. , 1963 , 3 , 69
3.
Walker
R.
, Anti-Corrosion , 1970 , 17 , 9
4.
Morito
N.
, &
Suetaka
W.
Jap. J. Inst. Metals , 1971 , 37 , 216
5.
Poling
G.
, Corros. Sci. , 1970 , 10 , 359
6.
Roberts
R. F.
, J. Electron Spectrosc. Related Phenomena , 1974 , 4 , 273
7.
Hoar
T. P.
, &
Holliday
R. D.
J. app!. Chem., Land. , 1953 , 3 , 502
8.
Frumkin
A. N.
, Z. phys. Chem. , 1925 , 116 , 466
9.
de Boer
J. H.
, ‘The Dynamical Character of Adsorption’ , 1953 (Oxford University Press)
10.
Parsons
R.
, J. electroanal. Chem. , 1964 , 7 , 136
11.
Damaskin
B. B.
, Petrii, 0. A., & Batrokov, V. V., ‘Adsorption of Organic Compounds ’, 1971 (New York : Plenum Press )
12.
Henry
D. C.
, Proc. R. Soc. Lond. , 1931 , A133, 106
13.
Freundlich
H.
, ‘Colloid and Capillary Chemistry’ , 1926 (London : Methuen Press Limited )
14.
Langmuir
I.
, J. Am. chem. Soc. , 1918 , 40 , 1369
15.
Volmer
M.
, Z. phys. Chem. , 1925 , 115 , 253
16.
Parsons
R.
, Trans. Faraday Soc. , 1925 , 5 1 , 1518
17.
Temkin
M. J.
, Zh. fiz. Khim. , 1941 , 15 , 296
18.
Helfand
E.
,
Frisch
H. L.
& Lebonitz. , J. chem. Phys. , 1961 , 34, 1037
19.
Lorentz
W.
,
Mockel
F.
, &
Muller
W.
Z. phys. Chem. , (N. F. ), 1960 , 25 , 145
20.
Blomgren
E.
, &
Bockris
J.
O'M. , J. phys. Chem. , 1959 , 63, 1475
21.
Hayward
D.
0., & Trapnell, B. H. W., Themisorption ’, 1964 , (Washington D.C .: Butterworths )
22.
Conway
B. E.
,
Dhar
H. P.
, &
Gottesfeld
S.
J. Colloid Interface Sci. , 1973 , 43 , 403
23.
Tompa
N.
, ‘Polymer Solutions’ , 1956 (London : Butterworths )
24.
Szklarska-Smialowska
Z.
, & Wieczorek, G. , Corros. Sci. , 1971 , 11 , 843
25.
Levine
B.
, &
Calvert
M.
Can. J. Chem. , 1962 , 40 , 518