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Abstract

Based on newly synthesized hydroquinone monomers, two series of halogenated polyaryletherketones, PEEKs and PEEKKs, were synthesized through nucleophilic aromatic substitution polycondensations. The chemical structures of the monomers and the polymers were carefully characterized using Fourier transform infrared and ¹H-NMR spectroscopies. Some interesting results about the relationships between the structure and properties of these polymers having comparable chemical structures were revealed for the first time. Despite the similar chemical structure of –F, –Cl and –Br substituted polyaryletherketones, they exhibited different thermal behaviors. The thermogravimetric analysis results showed that chlorinated PEEKK had the best thermal stability and its limited oxygen index (LOI) value was 42.80. The results indicated some of them will be promising high-performance polymers.

Keywords

polyaryletherketones halogenation thermal stability flame retardants

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References

Kurtz

Devine

. PEEK biomaterials in trauma, orthopedic, and spinal implants. Biomaterials 2007; 28: 4845–4869.

Godara

Raabe

Green

. The influence of sterilization processes on the micromechanical properties of carbon fiber-reinforced PEEK composites for bone implant applications. Acta Biomaterialia 2007; 3(2): 209–220.

Zhang

Awaja

James

. Autohesion of plasma treated semi-crystalline PEEK: Comparative study of argon, nitrogen and oxygen treatments. Colloids Surf A 2011; 374 (1–3): 88–95.

Mata

Gaitonde

Karnikc

. Influence of cutting conditions on machinability aspects of PEEK, PEEK CF 30 and PEEK GF 30 composites using PCD tools. J Mater Process Technol 2009; 209(4): 1980–1987.

Hickner

Ghassemi

Kim

. Alternative polymer systems for proton exchange membranes (PEMs). Chem Rev 2004; 104(10): 4587–4612.

Liu

Robertson

Kim

. Aromatic poly(ether ketone)s with pendant sulfonic acid phenyl groups prepared by a mild sulfonation method for proton exchange membranes. Macromolecules 2007; 40(6): 1934–1944.

Liu

Wang

. Poly(aryl ether ketone)s with (3-methyl)phenyl and (3-trifluoromethyl)phenyl side groups. Polym Chem 2002; 40(20): 3392–3398.

Zhao

Wang

. Cross-linkable fluorinated poly(ether ether ketone) polymers for optical waveguide devices. Mater Lett 2004; 58(19): 2365–2368.

Xiao

Cheg

Chung

. Asymmetric structure and enhanced gas separation performance induced by in situ growth of silver nanoparticles in carbon membranes. Carbon 2010; 48(2):408–416.

10.

Chen

Liu

Zhang

. Fabrication of fluorescent holographic micropatterns based on azobenzene-containing host-guest complexes. Langmuir 2009; 25(18): 10444–10446.

11.

Chen

Zhang

Liu

. Novel photoactive hyperbranched poly(aryl ether)s containing azobenzene chromophores for optical storage. J Mater Chem 2008; 18(41): 5019–5026.

12.

Liu

Robertson

Guiver

. Fluorinated poly(aryl ether) containing a 4-bromophenyl pendant group and its phosphonated derivative. Macromol Rapid Commun 2006; 27(17):1411–1417.

13.

Liu

Chen

. Soluble aromatic poly(ether ketone)s with a pendant 3,5-ditrifluoromethylphenyl group. Polymer 2004; 45(10): 3241–3247.

14.

Patel

Hull

McCabe

. Mechanism of thermal decomposition of poly(ether ether ketone) (PEEK) from a review of decomposition studies. Polym Degrad Stab 2010; 95(5): 709–718.

15.

Mallakpour

Zeraatpisheh

Sabzalian

. Sonochemical-assisted fabrication of biologically active chiral poly(ester-imide)/TiO₂ bionanocomposites derived from l-methionine and l-tyrosine amino acids. eXPRESS Polym Lett 2011; 5(9): 825–837 .

16.

Babanzadeh

Mahjoub

Mehdipour-Ataei

. Novel soluble thermally stable silane-containing aromatic polyimides with reduced dielectric constant. Polym Degrad Stabil 2010; 95(12): 2492–2498.

17.

Van Krevelen

Hoftyzer

. Properties of polymers. New York: Elsevier; 1976.

Halogenated polyaryletherketones with enhanced thermal stability

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