Static headspace gas chromatography–tandem mass spectrometry was used to identify volatile compounds from Senecio scandens Buch-Ham. The elemental composition of compounds was confirmed by exploiting the tandem mass spectra of isotopic peaks from the precursor ion. Some isomers were well distinguished by the diversified scan technologies of tandem mass spectrometry (MS/MS). The MS/MS included a product ion scan, a precursor ion scan and a neutral loss scan. The results showed that 46 volatile compounds were completely identified, and the great of majority compounds were α-pinene (11.93%), n-caproaldehyde (9.02%) and dehydrosabinene (6.22%). This qualitative method is convenient and accurate and can be considered as a complementary identification method for the qualitative analysis of volatile compounds in complex samples.
SuY.WangC.Z.GuoY.L., “Analysis of volatile compounds from Mentha hapioealyx Briq by GC-MS based on accurate mass measurement and retention index”, Acta Chim. Sinica67, 546 (2009).
2.
WangH.Y.GuoY.L., “Rapid analysis of the volatile compounds in the rhizomes of Rhodiold sachalinensis and Rhodiola sacra by static headspace-gas chromatography–tandem mass spectrometry”, Anal. Lett.37, 2151 (2004). doi: 10.1081/AL-200026690
3.
FangF.ChengZ.H.GuoY.L.CaiY.B., “Comparative analysis of the volatile components in the fresh roots and rhizomes of Curcuma wenyujin by static headspace gas chromatography mass spectrometry”, Chin. J. Chem.24, 1346 (2006).
ChenJ.P.GuM.WangY.D., “Improving the confidence of unknown compound identification by first responder mobile GC-MS laboratories in time-critical environmental and homeland security incidents”, LC GC North America26, 938 (2008).
6.
XuF.G.ZouL.LinQ.S.ChoonN.O., “Use of liquid chromatography/tandem mass spectrometry and online databases for identification of phosphocholines and lysophosphatidylcholines in human red blood cells”, Rapid Commun. Mass Spectrom.23, 3243 (2009). doi: 10.1002/rcm.4246
7.
ZhaoZ.Z.LuJ.LeungK.ChanC.L.JiangZ.H., “Determination of patchoulic alcohol in Herba pogostemonis by GC-MS-MS”, Chem. Pharm. Bull.53, 856 (2005).
8.
CapleyE.N.TiptonJ.D.MarshallA.G., “Chromatographic reduction of isobaric and isomeric complexity of fulvic acids to enable multistage tandem mass spectral characterization”, Anal. Chem.82, 8194 (2010). doi: 10.1021/ac1016216
9.
WangC.Z.SuY.GuoY.L., “Analysis of the volatile components from flowers and leaves of Osmanthus fragrans Lour. by headspace-GC-MS”, Chin. J. Org. Chem.29, 948 (2009).
10.
ZhuF.J.GuoY.L., “Analysis of the volatile components in the leaves of Cinnamomum camphora by static headspace gas chromatography mass spectrometry combined with accurate weight measurement”, Chin. J. Chem.28, 1451 (2010).
11.
LengJ.P.WangH.Y.ZhangL.ZhangJ.GuoY.L.“Application of tandem mass spectra for the peaks of isotope pattern in the elemental composition assignment of product ions”, Chin. J. Chem.28, 1751 (2010).
12.
LlorcaM.FarréM.PicóY.BarcelóD., “Study of the performance of three LC-MS/MS platforms for analysis of perfluorinated compounds”, Anal. Bioanal. Chem.398, 1145 (2010). doi: 10.1007/s00216-010-3911-5
13.
YaoM.MaL.DuchoslavE.ZhuM.S., “Rapid screening and characterization of drug metabolites using multiple ion monitoring dependent product ion scan and postacquisition data mining on a hybrid triple quadrupole–linear ion trap mass spectrometer”, Rapid Commun. Mass Spectrom.23, 1683 (2009). doi: 10.1002/rcm.4045
14.
JiangH.L.SomogyiA.TimmermannB.N.GangD.R., “Instrument dependence of electrospray ionization and tandem mass spectrometric fragmentation of the gingerols”, Rapid Commun. Mass Spectrom.20, 3089 (2006). doi: 10.1002/rcm.2699
15.
BatemanK.P.LockeS.J.VolmerD.A.“Characterization of isomeric sulfonamides using capillary zone electrophoresis coupled with nano-electrospray quasi-MS/MS/MS”, J. Mass Spectrom.32, 297 (1997). doi: 10.1002/(SICI)1096-9888(199703)32:3<297::AID-JMS485>3.0.CO;2-6
16.
ZhangJ.Y.WangY.DudkowskiC.YangD.C.ChangM.YuanJ.H.PaulsonS.K.BreauA.P., “Characterization of metabolites of Celecoxib in rabbits by liquid chromatography/tandem mass spectrometry”, J. Mass Spectrom.35, 1259 (2000). doi: 10.1002/1096-9888(200011)35:11<1259::AID-JMS57>3.0.CO;2-9
17.
ColzaniM.BienvenutW.V.FaesE.QuadronM., “Precursor ion scans for the targeted detection of stable-isotope-labeled peptides”, Rapid Commun. Mass Spectrom.23, 3570 (2009). doi: 10.1002/rcm.4287
18.
LydicT.A.BusikJ.V.EsselmanW.J.ReidG.E., “Complementary precursor ion and neutral loss scan mode tandem mass spectrometry for the analysis of glycerophosphatidylethanolamine lipids from whole rat retina”, Anal. Bioanal. Chem.394, 267 (2009). doi: 10.1007/s00216-009-2717-9
19.
ZhangX.ReidG.E., “Multistage tandem mass spectrometry of anionic phosphatidylcholine lipid adducts reveals novel dissociation Pathways”, Int. J. Mass Spectrom.252, 242(2006). doi: 10.1016/j.ijms.2006.04.001
20.
GadgilH.S.BondarenkoP.V.TreuheitM.J.RenD., “Screening and sequencing of glycated proteins by neutral loss scan LC/MS/MS method”, Anal. Chem.79, 5991 (2007). doi: 10.1021/ac070619k
21.
FerrerI.BarberL.B.ThurmanE.M., “Gas chromatographic–mass spectrometric fragmentation study of phytoestrogens as their trimethylsilyl derivatives: Identification in soy milk and wastewater samples”, J. Chromatogr. A1216, 6024 (2009). doi: 10.1016/j.chroma.2009.06.042
22.
QianR.LiaoY.X.GuoY.L., “ESI-FTICR-MS studies on gas phase fragmentation reactions of ArPd(PPh3)(2)I complexes”, J. Am. Soc. Mass Spectrom.17, 1582 (2006).
23.
HeZ.M.MengX.Y.BaoY.L.WuY.ZhuH.Y.LiY.X., “Antivirus effect of volatile oil from Senecio cannabifolius Less. and its constituents analysis”, Chinese J. Anal. Chem.10, 1513 (2007).
24.
SinghG.KapoorI.P.S.SinghO.P.RaoG.P.PrasadY.R.LeclercqP.A.KlinkbyN., “Studies on essential oils, part 28: Chemical composition, antifungal and insecticidal activities of rhizome volatile oil of Homalomena aromatica Schott”, Flavour Fragr J.15, 278 (2000). doi: 10.1002/1099-1026(200007/08)
25.
EdrisA.E., “Pharmaceutical and therapeutic potentials of essential oils and their individual volatile constituents: A review”, Phytother. Res.21, 308 (2007). doi: 10.1002/ptr.2072
26.
XiongA.Z.YangL.HeY.Q.ZhangF.WangJ.HanH.WangC.H.BlighS.W. AnnieWangZ.T.“Identification of metabolites of adonifoline, ahepatotoxic pyrrolizidine alkaloid, by liquid chromatography/tandem and high-resolution mass spectrometry”, Rapid Commun. Mass Spectrom.23, 3907 (2009). doi: 10.1002/rcm.4329
27.
WangC.Z.SuY.LiD.CaiB.GuoY.L., “Analysis of volatile organic compounds from Dendranthema indicum var. aromaticum by headspace gas chromatography–mass spectrometry and accurate mass measurement”, Anal. Lett.43, 2297 (2010). doi: 10.1080/00032711003717356
