A method for following chemical reactions in polymers, using the GC-IR software on an FT-IR spectrometer and a high-temperature thermal cell, is discussed. The method reduces disk access time between the collection of each spectrum, allowing many more data points for kinetic experiments to be collected. The imidization reaction of polyimides above 200°C is given as an example.
GinsburgR.SuskoJ. R., “Polyimide Curing Determination,” in Polyimides: Synthesis, Characterization and Applications, MittalK. L., Ed. (Plenum Press, New York, 1984), Vol. 1, pp. 237–247.
6.
NumataS.FujisakiK.KinjoN., “Studies of Thermal Cyclization of Polyamic Acids,” in Polyimides: Synthesis, Characterization and Applications, MittalK. L., Ed. (Plenum Press, New York, 1984), Vol. 1, pp. 259–271.
LaiusL. A.TsapovetskyM. I., “Kinetics and Mechanism of Thermal Cyclization of Polyamic Acids,” in Polyimides: Synthesis, Characterization and Applications, MittalK. L., Ed. (Plenum Press, New York, 1984), Vol. 1, pp. 295–309.
JinS.YangL.ZhuZ.ZhangZ.ZhuangQ., Conference Record of the 1985 International Conference on Properties and Applications of Dielectric Materials (IEEE Cat. No. 85CH2115–4)1, 104 (1985).
12.
YanigerS. I.VidrineD. W., Appl. Spectrosc.40, 174 (1986).