Aiming to improve the algorithm of the classic fuzzy C-means model (FCM), a double fuzzy C-means model (DFCM) was presented in this paper. A new fuzzy cluster validity index (RWW) and the DFCM algorithm were proposed, simultaneously. Then, the double fuzzy C-means model was applied for the clustering analysis of the regional technology innovation level in China. The validity of the double fuzzy C-means model was tested using the wine data set of UCI. The comparison results of different cluster validity indexes validated the fuzzy cluster validity index (RWW) proposed in this paper. The application example and wine data set clustering results indicated that the DFCM model enhanced the intra-class compactness and inter-class separation, making the classification more accurate.